1. Serena & Nate (GG)
2. Piper & Leo (Charmed)
3. Navid & Adrinna (90210) *most season 1*
4. Seth & Summer (OC)
5. Liam & Annie (90210)
6. Cleo & Lewis (H2O)
7. Phoebe & Cole (Charmed)
8. Chuck & Blair (GG)
9. Ryan & Marissa (OC)
10. Dan & Vanessa (GG)
11. Monica & Chandler (Friends)
12. Prue & Andy (Charmed)
13. Rikki & Zane (H2O)
14. Silver & Dixon (90210)
15. Carly & Freddie (iCarly)
16. Rufus & Lily (GG)
17. Dan & Serena (GG) *ONLY Season 1*
18. Ross & Rachel (Friends)
19. Brenda & Dylan (BH 90210)
20. Susan & Mike (DH)
21. Blair & Nate (GG)
22. Luke & Lorelai (GG)
23. Rogan & Jess (GG)
24. Phoebe & Mike (Friends)
25. Paige & Henry (Charmed)

i don't ship most of them.. but i guess i like them :D

In no particular order:
1. House and Cuddy (House, M.D.) OTP!
2. Mac and Stella (CSI: NY)
3. Brennan and Booth (Bones)
4. Tony and Ziva (NCIS)
5. Hotchner and Prentiss (Criminal Minds)
6. Catherine and Grissom (CSI)
7. Meredith and Derek (Grey's Anatomy)
8. Sam and Addison (Private Practice)
9. Mulder and Scully (The X-Files)
10. Piper and Leo (Charmed)
11. Spike and Buffy (BTVS)
12. Kira and Odo (ST: DS9)
13. Riker and Troi (ST: TNG)
14. Monica and Chandler (Friends)
15. Martin and Sam (Without a Trace)
16. Lily and Scotty (Cold Case)
17. Benson and Stabler (L&O: SVU)
18. Wilson and Sam (House)
19. Chase and Cameron (House)
20. Danny and Lindsay (CSI: NY)
21. Flack and Angell (CSI: NY)
22. Cole and Phoebe (Charmed)
23. Reid and Jareau (Criminal Minds)
24. Max and Tara (The United States of Tara)
25. Alex and Izzie (Grey's Anatomy)

1. Jake & Peyton (One Tree Hill)
2. Sawyer & Kate (Lost)
3. Rory & Jess (Gilmore Girls)
4. Ryan & Marissa (The OC)
5. Brandon & Kelly (Beverly Hills 90210)
6. Liam & Naomi (90210)
7. Serena & Nate (Gossip Girl)
8. Freddie & Effy (Skins)
9. Alex & Izzie (Grey`s Anatomy)
10. Puck & Quinn (Glee)
11. Jim & Pam (The Office)
12. Matt & Caroline (The Vampire Diaries)
13. Luke & Lorelai (Gilmore Girls)
14. Seth & Summer (The OC)
15. Dylan & Brenda (BH 90210)
16. Tony & Michelle (Skins)
17. Sookie & Eric (True Blood)
18. Damon & Elena (The Vampire Diaries)
19. Brooke & Lucas (OTH)
20. Adrianna & Navid (90210)
21. Charlie & Claire (Lost)
22. Jesse & Rachel (Glee)
23. Mark & Callie (Grey`s Anatomy)
24. David & Donna (BH 90210)
25. Danny & Mia (Degrassi)

I'll do this again as it's over a year since I did it the last time LOL

01. Jake & Peyton (One Tree Hill)
02. Chuck & Sarah (Chuck)
03. Jack & Kate (Lost)
04. Seth & Summer (The OC)
05. Rory & Jess (Gilmore Girls)
06. John & Mary (Supernatural)
07. Chandler & Monica (Friends)
08. Nathan & Haley (One Tree Hill)
09. Sookie & Eric (True Blood)
10. Charlie & Claire (Lost)
11. Dean & Jo (Supernatural)
12. Marshall & Lily (How I Met Your Mother)
13. Luke & Lorelai (Gilmore Girls)
14. Desmond & Penny (Lost)
15. Sin & Jun (Lost)
16. Barney & Robin (How I Met Your Mother)
17. Logan & Veronica (Veronica Mars)
18. Ryan & Taylor (The OC)
19. Brooke & Julian (One Tree Hill)
20. Tony & Michelle (Skins)
21. Phoebe & Mike (Friends)
22. Emily & Naomi (Skins)
23. Puck & Rachel (Glee
24. Puck & Quinn (Glee)
25. Will & Emma (Glee)

Not sure if that will be my exact order, but ah well

This is my most recent top 25 couples in no order :)

1. Quinn and Puck (Glee)
2. Rachel and Puck (Glee)
3. Rachel and Finn (Glee)
4. Buffy and Angel (BTVS)
5. Sookie and Eric (True Blood)
6. Silver and Dixon (90210)
7. John and Mary (Supernatural)
8. Dean and Jo (Supernatural)
9. Lily and Marshall (HIMYM)
10. Piper and Leo (Charmed)
11. Phoebe and Cole (Charmed)
12. Rachel and Ross (Friends)
13. Effy and Cook (Skins)
14. Susan and Mike (Desperate Housewives)
15. Peyton and Lucas (OTH)
16. Nathan and Haley (OTH)
17. Brooke and Julian (OTH)
18. Izzie and Alex (GA)
19. Addison and Mark (GA)
20. Brenda and Dylan (Beverly Hills 90210)
21. Martha and Jack (H&A)
22. Elena and Damon (TVD)
23. Elena and Stefan (TVD)
24. Caroline and Matt (TVD)
25. Anna and Jeremy (TVD)

1.Buffy and Spike(BTVS)
2.Logan and Veronica(Veronica Mars)
3.Mal and Inara(Firefly)
4.Castle and Beckett(Castle)
5.Tony and Ziva(NCIS)
6.Pacey and Joey(Dawson's Creek)
7.Kelly and Dylan(BH 90210)
8.Baze and Cate(Life Unexpected)
9.Tim and Lyla(FNL)
10.Shawn and Juliet(Psych)
11.Damon and Elena(TVD)
12.Serena and Nate(Gossip Girl)
13.Quinn and Puck(Glee)
14.Phoebe and Cole(Charmed)
15.Matt and Caroline(TVD)
16.Elena and Stefan(TVD)
17.Caroline and Tyler(TVD)
18.Sookie and Eric(True Blood)
19.Serena and Carter(Gossip Girl)
20.Mark and Lexie(Grey's Anatomy)
21.Liam and Annie(90210)
22.Justin and Rebecca(Brothers & Sisters)
23.Jake and Peyton(OTH)
24.Xander and Anya(BTVS)
25.Tyler and Caroline(TVD)

My favourite couples in order? Let me see:
1/2 Booth and Brennan - OTP (Bones)
1/2 Brucas - OTP (OTH)
3. Jack and Kate (Lost)
4. Meredith and Derek (Greys Anatomy)
5. Brooke and Julian (OTH)
6. Logan and Veronica (Veronica Mars)
7. Ross and Rachel (Friends)
8. Charlie and Claire (lost)
9. Michael and Sara (Prison Break)
10. Denny and Izzie (GA)
11. Jake and Peyton (OTH)
12. Nathan and Haley (OTH)
13. Duncan and Veronica (VM)
14. Hodgins and Angela (bones)
15. Tru and Jack (Tru Calling)
16. Mia and Manuel (Rebelde Way)
17. Monica and Chandler (Friends)
18. Caroline and Agent Ballard (Dollhouse)
19. Stefan and Elena (The Vampire diaries)
20. Paige and Kyle (Charmed)
21. Charlotte and Daniel (Lost)
22. Phoebe and Mike
23. Karen and Keith (OTH)
24. Xena and Aris (Xena the warrior princess)
25. Alex and Izzie (GA)

Ok they are in order and it was kind of hard after number 20!

1. Haley & Nathan (OTH)
2. Brooke & Lucas (OTH)
3. Rachel & Ross (Friends)
4. Jake & Peyton (OTH)
5. Amy & Ricky (Secret Life)
6. Joey & Pacey (Dawson's Creek)
7. Matt & Caroline (TVD)
8. Damon & Bonnie (TVD)
9. Seth & Summer (The OC)
10. Marissa & Ryan (The OC)
11. Stefan & Elena (TVD)
12. Monica & Chandler (Friends)
13. Donna & David (BH. 90210)
14. Angel & Buffy (BTVS)
15. Dylan & Kelly (BH, 90210)
16. Lorelai & Luke (Gilmore Girls)
17. Rory & Logan (Gilmore Girls)
18. Sookie & Bill (True Blood)
19. Jessica & Hoyt (True Blood)
20. Sam and Jess (Supernatural)
21. Puck & Quinn (Glee)
22. Dean & Bela (SPN)
23. Baze & Cate (Life Unexpected)
24. Kevin & Lucy (7th Heaven)
25. Rachel & Finn (Glee)

1.Chuck&Blair(Gossip Girl)
2.Dan&Serena(Gossip Girl)
3.Nate&Jenny(Gossip Girl)
4.Quinn&Puck(Glee)
5.Amy&Ricky(The Secret Life of the American Teenager)
6.Ben&Adrian(The Secret Life of the American Teenager)
7.Finn&Rachel(Glee)
8.Nate&Vanessa(Gossip Girl)
9.Damon&Elena(The Vampire Diaries)
10.Dan&Blair(Gossip Girl)
11.Chuck&Jenny(Gossip Girl)
12.Navid&Adrianna(90210)
13.Liam&Annie(90210)
14.Silver&Dixon(90210)
15.Chuck&Vanessa(Gossip Girl)
16.Chuck&Serena(Gossip Girl)
17.Dan&Georgina(Gossip Girl)
18.Chuck&Georgina(Gossip Girl)
19.Jay&Manny(Degrassi)
20.Declan&Holly J(Degrassi)
21.Peter&Mia(Degrassi)
22.Sav&Anya(Degrassi
23.Jack&Grace(The Secret Life of the American Teenager)
24.Colby&Damon(All My Children)
25.Matt&Caroline(The Vampire Diaries)

1. Effy & Freddie {Skins}
2. Dan & Serena {Gossip Girl}
3. Chuck & Blair {Gossip Girl}
4. Dan & Blair {Gossip Girl}
5. Chuck & Jenny {Gossip Girl}
6. Sid & Michelle {Skins}
7. Chuck & Vanessa {Gossip Girl}
8. Cook & Emily {Skins}
9. Emily & JJ {Skins}
10. Tony & Michelle {Skins}
11. Ben & Amy {Secret Life}
12. Ricky & Amy {Secret Life}
13. Jim & Pam {The Office}
14. Jenny & RJ {The Hard Times of RJ Berger}
15. Sonny & Chad {Sonny With A Chance}
16. Carly & Freddie {iCarly}
17. Finn & Rachel {Glee}
18. Puck & Quinn {Glee}
19. Will & Emma {Glee}
20. Nate & Jenny {Gossip Girl}
21. Nate & Vanessa {Gossip Girl}
22. Tony & Maxxie {Skins}
23. Cook & Freddie {Skins}
24. Shawn & Jules {Psych}
25. Aria & Ezra {PLL}

so i basically ship everyone on Gossip Girl lol, this was hard!

Without any particular order after #5.

1.Jack&Kate {lost}
2.Jake and Peyton {oth}
3.Peter&Olivia {fringe}
4.Seth&Summer {the oc}
5.Monica&Chandler {friends}
6.Ross&Rachel {friends}
7.Desmond&Penny {lost}
8.Ryan&Taylor {the oc}
9.Charlie&Claire {lost}
10.Sun&Jin {lost}
11.Sawyer&Juliet {lost}
12.Nathan&Haley {oth}
13.Sid&Cassie{skins}
14.Dan&Serena {gossip girl}
15.Will&Emma {glee}
16.Quinn&Puck {glee]
17.Phoebe&Mike {friends}
18.Carrie&Big {sex and the city}
19.Carter&Abby {er}
20.Susan&Mike {desperate houseviwes}
21.Meredith&Derek (grey's anatomy}
22.Alex&Izzie {grey's anatomy}
23.Mark&Lexie {grey's anatomy}
24.Cristina&Owen {grey's anatomy}
25.Callie&Arizona {grey's anatomy}

I'm gonna try this... In No Order

1. Huddy [House]
2. B&B [Bones]
3. Leyton [OTH]
4. Cassid [Skins]
5. Freffy [Skins]
6. Swarkles(RoBarn, BaRobin, Bobin, Robney, BAR, etc.) [HIMYM]
7. St. Berry [Glee]
8. Quick [Glee]
9. C&C [Greek]
10. LAME [HIMYM]
11. Naley [OTH]
12. Chris & Jal [Skins]
13. Naomily [Skins]
14. Chameron [House]
15. Wemma [Glee]
16. Brulian [OTH]
17. Hameron [House]
18. Piper & Leo [Charmed]
19. Shenny [TBBT]
20. Angela & Jordan [MSCL]
21. Shawn & Juliet [Psych]
22. Victor & Sierra [Dollhouse]
23. Angela & Hudgins [Bones]
24. Jeyton [OTH]
25. JAM [The Office]

That's for now. I'll be back in a year to see what changed :P

MY LIST.♥ [Not exactly in order]♥

Damon and Elena {Vampire Diaries} ♥
Jack and Kate {Lost} ♥
Brooke and Lucas {One Tree Hill} ♥
Cook and Effy {Skins} ♥
Puck and Rachel {Glee} ♥
Darren and Hanna {Pretty Little Liars} ♥
Serena and Nate {Gossip Girl} ♥
Phoebe and Cole {Charmed} ♥
Tyler and Bonnie {Vampire Diaries} ♥
Sookie and Eric {True Blood} ♥
Spike and Buffy {Buffy The Vampire Slayer} ♥
Dean and Jo {Supernatural} ♥
Monica and Chandler {Friends} ♥
Charlie and Claire {Lost} ♥
Desmond and Penny {Lost} ♥
Nathan and Brooke {One Tree Hill} ♥
Harry and Hermione {Harry Potter} ♥
Jeremy and Anna {Vampire Diaries} ♥
Paige and Kyle {Charmed} ♥
Andy and Prue {Charmed} ♥
Warren and Louise {Hollyoaks} ♥
Silver and Ethan {90210} ♥
Will and Emma {Glee} ♥
Jack and Ronnie {Eastenders} ♥
Liam and Naomi {90210} ♥

1. Damon & Elena (The Vampire Diaries)
2. Michael & Nikita (La Femme Nikita)
3. Sawyer & Kate (Lost)
4. Logan & Veronica (Veronica Mars)
5. House & Cuddy (House MD)
6. Matt & Caroline (The Vampire Diaries)
7. Jeremy & Anna (The Vampire Diaries)
8. Desmond & Penny (Lost)
9. Jack & Kate (Lost)
10. Sawyer & Juliet (Lost)
11. Melinda & Jim (Ghost Whisperer)
12. Michael & Sara (Prison Break)
13. Eric & Sookie (True Blood)
14. Charlie & Claire (Lost)
15. Ross & Rachel (Friends)
16. Chandler& Monica (Friends)
17. Cappie & Casey (Greek)
18. Chuck & Blair (Gossip Girl)
19. Chuck & Sara (Chuck)
20. Olivia & Peter (Fringe)
21. Wilson & Amber (House MD)
22. Penny & Sheldon (The Big Bang Theory)
23. Sayid & Shannon (Lost)
24. Ryan & Taylor (The OC)
25. Stefan & Elena (The Vampire Diaries)

-Not in order, except #1-

1. Shawn♥Juliet-Psych
2. Castle♥Beckett-Castle
3. Booth♥Brennan-Bones
4. Jack♥Angela-Bones
5. Sweets♥Daisy-Bones
6. Esposito♥Lanie-Castle
7. Sam♥Freddie-iCarly
8. Peter♥Olivia-Fringe
9. Jim♥Melinda-Ghost Whisperer
10. Penny♥Sheldon-Big Bang Theory
11. Amy♥Ty-Heartland
12. Peter♥Lou-Heartland
13. Ezra♥Aria-Pretty Little Liars
14. Pam♥Jim-The Office
15. Dwight♥Angela-The Office
16. Micheal♥Holly-The Office
17. McGee♥Abby-NCIS
18. Stefan♥Elena-Vampire Diaries
19. Tony♥Ziva-NCIS
20. Piper♥Leo-Charmed
21. Sookie♥Bill-True Blood

I don't really have any more =P

Not in order, except for the first 3.

1. Spike/Buffy (BtVS)
2. Booth/Brennan (Bones)
3. Damon/Elena (Vampire Diaries)
4. Chuck/Blair (Gossip Girl)
5. Cordelia/Doyle (Angel)
6. Barney/Robin (How I Met Your Mother)
7. Buffy/Angel (BtVS)
8. Fred/Wesley (Angel)
9. Beckett/Castle (Castle)
10. Gwen/Arthur (Merlin)
11. Merlin/Arthur (Merlin)
12. Rachel/Puck (Glee)
13. Willow/Oz (BtVS)
14. Willow/Tara (BtVS)
15. Xander/Anya (BtVS)
16. Xander/Cordelia (BtVS)
17. Cordelia/Angel (Angel)
18. Faith/Angel (Angel)
19. Spike/Dru (BtVS)
20. Tina/Artie (Glee)
21. Pam/Jim (Office)
22. Britta/Jeff (Community)
23. Jenny/Giles (BtVS)
24. Ted/Robin (How I Met Your Mother)
25. Tony/Ziva (NCIS)

In order-ish. They switch up depending on which show I saw last. Non-plausible couples are included.

1. Shawn and Juliet (Psych)
2. Brennan and Booth (Bones)
3. Kutner and Thirteen (House)
4. McGee and Abby (NCIS)
5. Hotch and Emily (Criminal Minds)
6. Peter and Olivia (Fringe)
7. Tony and Ziva (NCIS)
8. Wilson and Cameron (House)
9. Jack and Renee (24)
10. Cal and Gillian (Lie to Me)
11. House and Cuddy (House)
12. Tony and Kate (NCIS)
13. Loker and Torres (Lie to Me)
14. Reid and JJ (Criminal Minds)
15. Lassiter and the Chief (Psych)
16. Carter and Joe (Eureka)
17. Milo and Nadia (24)
18. Tony and Michelle (24)
19. Chase and Thirteen (House)
20. Gibbs and M. Allison Hart (NCIS)
21. Charlie and Olivia (Fringe)
22. Hotch and Elle (Criminal Minds)
23. Auggie and Annie (Covert Affairs)
24. Sweets and Angela (Bones)
25. Wilson and Thirteen (House)

Not in order except for #1.

1. Sawyer and Kate(Lost)<3
2. Charlie and Claire(Lost)
3. Desmond and Penny(Lost)
4. Shannon and Sayid(Lost)
5. Chuck and Blair(Gossip Girl)
6. Dan and Serena(Gossip Girl)
7. Lucas and Peyton(One Tree Hill)
8. Rachel and Ross(Friends)
9. Monica and Chandler(Friends)
10. Nate and Jenny(Gossip Girl)
11. Aria and Noel(Pretty Little Liars)
12. Spencer and Alex(Pretty Little Liars)
13. Hannah and Sean(Pretty Little Liars)
14. Holly J. and Declan(Degrassi)
15. Spinner and Jane(Degrassi)
16. Mia and Peter(Degrassi)
17. Lorelai and Luke(Gilmore Girls)
18. Rory and Jess(Gilmore Girls)
19. Adrian and Ben(The Secret Life)
20. Ricky and Amy(The Secret Life)
21. Jack and Grace(The Secret Life)
22. Pam and Jim(The Office)
23. Liz and Jack(The Office)
24. Jesse and Rebecca(Full House)
25. DJ and Steve(Full House)

That was hard!!!

The first 3 couples are in order the others not so much I think.

1. Chuck and Blair (Gossip Girl)
2. Seth and Summer (The O.C.)
3. Ross and Rachel (Friends)
4. Alex and Izzie (Greys Anatomy)
5. Dan and Blair (Gossip Girl)
6. Damon and Elena (The Vampire Diaries)
7. Nate and Serena (Gossip Girl)
8. Chandler and Monica (Friends)
9. Puck and Rachel (Glee)
10. Freddie and Effy (Skins)
11. Dan and Serena (Gossip Girl)
12. Arizona and Callie (Greys Anatomy)
13. Foreman and 13 (House M.D.)
14. Lucas and Brooke (One Tree Hill)
15. Ryan and Marissa (The O.C.)
16. Hyde and Jackie (That 70s Show)
17. JD and Elliot (Scrubs)
18. Doug and Carrie (The King of Queens)
19. Barney and Robin (How I Met Your Mother)
20. Charlie and Rose (Two and a half Men)
21. Alan and Judith (Two and a half Men)
22. Jeremy and Vicky (The Vampire Diaries)
23. Phoebe and Joey (Friends)
24. Ryan and Taylor (The O.C.)
25. Quinn and Puck (Glee)

the first ones are in order, but the next ones not really :D

1.Damon&Elena (VD)
2.Freddie&Effy (Skins)
3.Tim&Lyla (Friday night lights)
4.Puck&Quinn (Glee)
5.Eric&Sookie (True blood)
6.Kate&Jack (Lost)
7.Toby&Emily(Pretty little liars)
8.Henry&Anne (The tudors)
9.Dan&Serena (Gossip Girl)
10.House&Cuddy (House)
11.Nate&Blair (Gossip girl)
12.Cristina&Burke (Grey's anatomy)
13.Tony&Michelle (Skins)
14.Dan&Blair (Gossip girl)
15.Cris&Jal (Skins)
16.Spencer&Wren/Alex (Pretty little liars)
17.Will&Emma (Glee)
18.Rachel&Jesse (Glee)
19.Lucas&Peyton (OTH)
20.Arthur&Morgana (Merlin)
21.Merlin&Gwen (Merlin)
22.Seth&Summer (OC)
23.Stefan&Bonnie (VD)
24.Richard&Kahlan (LOTS)
25.Chase&Cameron (House)

hard.. but i'm gonna try:

1. Buffy&Angel [Buffy the vampire slayer]
2. Nate&Serena [Gossip Girl]
3. Damon&Elena [The Vampire Diaries]
4. Puck&Quinn [Glee]
5. Meredith&Derek [Grey's Anatomy]
6. Chuck&Serena [Gossip Girl]
7. Eric&Sookie [True Blood]
8. Cook&Effy [Skins]
9. Ross&Rachel [FRIENDS]
10. Brooke&Lucas [One Tree Hill]
11. Chuck&Blair [Gossip Girl]
12. Rory&Jess [Gilmore Girls]
13. Effy&Freddie [Skins]
14. Naomi&Emily [Skins]
15. Ryan&Marissa [The OC]
16. Pheobe&Cole [Charmed]
17. Seth&Summer [The OC]
18. Dylan&Brenda [Beverly Hills 90210]
19. Monica&Chandler [FRIENDS]
20. Nathan&Haley [One Tree Hill]
21. Chuck&Jenny [Gossip Girl]
22. Matt&Caroline [The Vampire Diaries]
23. Jessica&Hoyt [True Blood]
24. Piper&Leo [Charmed]
25. Carter&Serena [Gossip Girl]

F$%@, this will be hard.

But here goes, with no order in mind.

1) Barney and Robin - How I Met Your Mother
2) Rachel and Jesse - Glee [OTP]
3) Phoebe and Cole - Charmed
4) Meredith and Derek - Grey's Anatomy
5) Puck and Quinn - Glee
6) Marshall and Lily - How I Met Your Mother
7) Veronica and Logan - Veronica Mars
8) Piper and Leo - Charmed
9) Rachel and Finn - Glee (And people have asked me: How can you be a St. Berry AND Finchel shipper, and I say: Watch the freaking finale!!)
10) Will and Emma - Glee
11) Paige and Kyle - Charmed
12) Sookie and Eric - True Blood
13) Sylar and Elle - Heroes
14) Cristia and Burke - Grey's Anatomy (The show SUCKED without him.)
15) Sookie and Bill - True Blood
16) Prue and Andy - Charmed
17) Jim and Pam - The Office
18) Dwight and Angela - The Office
19) Angela and Andy - The Office
20) Andy and Erin - The Office
21) Michael and Holly - The Office
22) Hilda and Santos - Ugly Betty *sob*
23) Tina and Artie - Glee
24) Santana and Brittany - Glee
25) Sawyer and Juliet - Lost

(Can I PLEASE add more?!)

1. Lucas & Peyton - OTH

2. Sawyer & Kate - Lost
2. Dan & Serena -GG
4. Chuck & Blair - GG
3. Damon & Elena -TVD
6. Seth & Summer - The OC
7. Rory & Jess - Gilmore Girls
8. Sookie & Eric - True Blood
9. Sydney & Vaughn - Alias
10.Veronica & Logan -Veronica Mars

11. Dean & Jo - Supernatural
12. Booth & Brennan - Bones
13. Buffy & Angel - BTVS
14. Dan & Blair - Gossip Girl
15. Tony & Ziva - NCIS
16. Michael & Sara - Prison Break
17. Tim & Lyla - FNL
18. Puck & Quinn - Glee
19. Michael & Maria - Roswell
20. Pacey & Joey - Dawson´s creek
21. Brooke & Julian - OTH
22. Alex & Izzie - GA
23. Monica & Chandler - Friends
24. Peter & Olivia - Fringe
25. Nathan & Haley - OTH

Not in order

1.Veronica and Logan(Veronica Mars)
2.Serena and Nate(GG)
3.Buffy and Spike(BTVS)
4.Liam and Annie(90210)
5.Sid and Cassie(Skins)
6.Kelly and Dylan(BH 90210)
7.Mal and Inara(Firefly)
8.Baze and Kate(Life Unexpected)
9.Casey and Evan(Greek)
10.Pacey and Joey(Dawson's Creek)
11.Tim and Lyla(FNL)
12.Rebecca and Justin(B&S)
13.Tony and Ziva(NCIS)
14.Castle and Beckett(Castle)
15.Puck and Quinn(Glee)
16.Phoebe and Cole(Charmed)
17.Carter and Serena(GG)
18.Matt and Caroline(TVD)
19.Marka and Lexie(GA)
20.Katherine and Stefan(TVD)
21.Shawn and Juliet(Psych)
22.Damon and Elena(TVD)
23.Eric and Sookie(TB)
24.Jake and Peyton(OTH)
25.Casey and Cappie(Greek)

Okay, so this list may kick my ass b/c It's really hard for me after the top 5. But here we go:
Some are non-canon couples!

1. BANGEL!!! Buffy/Angel (BtVS)
2. Tiva- Tony/Ziva (NCIS)
3. Kara/Lee (BSG)
4. WOz- Willow/Oz (BtVS)
5. Shenny- Sheldon/Penny (Big Bang Theory)
6. Doctor/Rose (Doctor Who)
7. M&M- Michael/Maria (Roswell)
8. Suliet- Sawyer/Juliet (Lost)
9. Phole- Phoebe/Cole (Charmed)
10. Leyton- Lucas/Peyton (OTH)
11. Huddy- House/Cuddy (House md)
12- Hodgins/Angela (Bones)
13- Max/Liz (Roswell)
14. Luke/Lorelai (Gilmore Girls)
15. Will/Grace- Will & Grace (NOT as a sexual relationship, but you have to admit they are definitely soulmates, I don't believe your soulmate has to be a significant other, so NOT sexually!)
16. Sabrina/Harvey (Sabrina the Teenage Witch)
17. Marshall/Lilly (How I Met Your Mother)
18. Robin/Barney (HIMYM)
19. Sierra/Victor (Dollhouse)
20. Helo/Athena- Carl/Sharon (BSG)
21. Joan/Ryan (Joan of Arcadia)

Don't think I can do any more, how about the last few are from books? Work for you? Good!

22. Dramoine- Draco/Hermoine (Harry Potter)
23. Bella/Edward (Twilight [Buffy and Angel are def the original and way better though])
24. Westley(this is the correct spelling)/Buttercup (The Princess Bride [It was a book first people!])
25. Harry/Ginny (Harry Potter)

Going over my list it seems a little unconventional, I ship a lot of non-canon couples I guess, haha.

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1) Niles & Daphne – Frasier
2) Meredith & Derek – Grey’s Anatomy
3) House & Cuddy – House M.D
4) Will & Emma – Glee
5) Susan & Mike – Desperate Housewives
6) Luke & Lorelai – Gilmore Girls
7) Fran & Max – The Nanny
8) Lucy & Ricky – I Love Lucy
9) Callie & Arizona – Grey’s Anatomy
10) Buffy & Angel - Buffy the Vampire Slayer
11) Frasier & Charlotte – Frasier
12) Grissom & Sara – CSI
13) Chandler & Monica – Friends
14) Ned & Charlotte – Pushing Daisies
15) Bette & Tina – The l Word
16) Ross & Rachel – Friends
17) Miranda & Steve – Sex and the City
18) Katherine & Robin – Desperate Housewives
19) Turk & Carla – Scrubs
20) Castle & Beckett – Castle
21) Carla & Hanna – Verboteneliebe
22) Sam & Diane – Cheers
23) Martin & Rony – Frasier
24) Mulder & Skully – The X Files
25) Xena & Gabrielle - Xena: Warrior Princess

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1. Brandon and Kelly (Beverly Hills 90210)OTP
2. Logan and Veronica (Veronica Mars)
3. Sean and Emma (Degrassi)
4. David and Donna (Beverly Hills 90210)
5. Brooke and Lucas (One Tree Hill)
6. Ryan and Taylor (OC)
7. Haley and Nathan (One Tree Hill)
8. Seth and Summer (OC)
9. Jay and Manny (Degrassi)
10. Sid and Cassie (Skins)
11. JT and Liberty (Degrassi)
12. Jake and Peyton (One Tree Hill)
13. Jackie and Hyde (That 70's Show)
14. Piper and Leo (Charmed)
15. Cory and Topanga (Boy Meets World)
16. Lorelei and Luke (Gilmore Girls)
17. Chuck and Blair (Gossip Girl)
18. Steve and Janet (Beverly Hills 90210)
19. Alex and Izzie (Grey's Anatomy)
20. Dylan and Toni (Beverly Hills 90210)
21. Sandy and Kirsten (The OC)
22. Lily and Marshall (HIMYM)
23. Phoebe and Cole (Charmed)
24. Charlie and Claire (Lost)
25. Chris and Jal (Skins)

I reserve the right to change my mind!

1. clark n lana (SV)
2. nate n serena (GG)
3. sam n quinn (Glee)
4. stefan n elena (TVD)
5. flack n angel (CSI NY)
6. mike n susan (DH)
7. chuck n sarah (Chuck)
8. artie n brittany (Glee)
9. jeremy n anna (TVD)
10. matt n caroline (TVD)
11. jack n juliet (Lost)
12. charlie n claire (Lost)

1. Tony and Ziva (NCIS)
2. Mulder and Scully (The X Files)
3. Peter and Olivia (Fringe)
4. Castle and Beckett (Castle)
5. Chuck and Sarah (Chuck)
6. Spike and Buffy (Buffy the Vampire Slayer)
7. Simon and Alisha (Misfits)
8. Nathan and Kelly (Misfits
9. Barney and Robin (How I met Your Mother)
10. Shawn and Juliet (Psych)
11. McGee and Abby (NCIS)
12. Cory and Topanga (Boy Meets World)
13. Hank and Karen (Californication)
14. Jack and Kate (Lost)
15. Booth and Brennan (Bones)
16. Bernard and Rose (Lost)
17. Hotch and Emily (Criminal Minds)
18. Daniel and Charlotte (Lost)
19. Niles and Daphne (Frasier)
20. Piper and Leo (Charmed)
21. Lilah and Wesley (Angel)
22. Penny and Sheldon (The Big Bang Theory)
23. Sookie and Eric (True Blood)
24. House and Cuddy (House MD)
25. Hurley and Libby (Lost)

A bit of a hard question but i'll give it a try.

1.Mike and Susan(Desperate Housewives)
2.Zack and Kelly(Saved By The Bell)
3.Seth and Summer(The OC)
4.Dylan and Brenda(Beverly Hills 90210)
5.Pacey and Joey(Dawson's Creek)
6.Alex and Izzie(Grey's Anatomy)
7.Chase and Cameron(House)
8.Cory and Topanga(Boy Meets World)
9.Luke and Marissa(The OC)
10.Angel and Buffy(Buffy)
11.Bernard and Rose(Lost)
12.Sawyer and Kate(Lost)
13.Jackie and Kelso(That 70s'Show)
14.Sandy and Kirsten(The OC)
15.Eric and Annie(7th Heaven)
16.Kitty and Red(That 70s Show)
17.Slater and Jessie(Saved By The Bell)
18.Lucas and Brooke(One Tree Hill)
19.Mick St.John and Beth(Moonlight)
20.Logan and Veronica(Veronica Mars)
21.Hurley and Libby(Lost)
22.Brandon and Kelly(Beverly Hills 90210)
23.Ryan and Marissa(The OC)
24.David and Donna(Beverly Hills 90210)
25.Dr.House and Dr.Cuddy(House)

Here are mine, from No. 2 on in no particular order:

1. Chloe & Oliver (Smallville) - My OTP
2. Lois & Clark (Smallville)
3. Booth & Brennan (Bones)
4. Wesley & Fred (Angel)
5. Veronica & Duncan (Veronica Mars)
6. Tru & Luc (Tru Calling)
7. Danny & Lindsay (CSI NY)
8. Callie & Arizona (Grey's Anatomy)
9. Pete & Addison (Private Practice)
10. Cole & Phoebe (Charmed)
11. Tony & Ziva (NCIS)
12. Jack & Annabeth (Close To Home) - if only for the fact that Jack is played by Christian Kane ;)
13. Sydney & Vaughn (Alias)
14. Lindsey & Eve (Angel)
15. Mark & Lexie (Grey's Anatomy)
16. Doug & Carol (ER)
17. Luka & Abby (ER)
18. Martin & Samantha (Without A Trace)
19. Dharma & Greg (Dharma & Greg)
20. George & Constance (North and South) - one of the first couples I shipped
21. Oliver & Lois (Smallville)
22. Eddie & Shaunie (Baywatch)
23. Deanna & Will (Star Trek - TNG)
24. Beverly & Jean-Luc (Star Trek - TNG)
25. Meredith & Derek (Grey's Anatomy)

1 ; Monica & Chandler (Friends)
2 ; Mark & Lexie (Grey's Anatomy)
3 ; Piper & Leo (Charmed)
4 ; Nathan & Haley (One Tree Hill)
5 ; Leonard & Penny (The Big Bang Theory)
6 ; Ross & Rachel (Friends)
7 ; Brittany & Santana (Glee)
8 ; Jackson & April (Grey's Anatomy)
9 ; Barney & Robin (How I Met Your Mother)
10 ; Nick & Jess (New Girl)
11 ; Callie & Arizona (Grey's Anatomy)
12 ; Niles & CC (The Nanny)
13 ; Kurt & Blaine (Glee)
14 ; Howard & Bernadette (The Big Bang Theory)
15 ; Brooke & Lucas (One Tree Hill)
16 ; Steve & Miranda (Sex And The City)
17 ; Sheldon & Amy (The Big Bang Theory)
18 ; Nate & Serena (Gossip Girl)
19 ; Meredith & Derek (Grey's Anatomy)
20 ; Marshall & Lily (How I Met Your Mother)
21 ; Alex & Izzie (Grey's Anatomy)
22 ; Sam & Quinn (Glee)
23 ; Mike & Phoebe (Friends)
24 ; Tony & Ziva (NCIS)
25 ; Lucas & Peyton (One Tree Hill)

Honorable Mentions:
26 ; Mike & Susan (Desperate Housewives)
27 ; Teddy & Henry (Grey's Anatomy)
28 ; Will & Emma (Glee)
29 ; Phoebe & Cole (Charmed)
30 ; Maxwell & Fran (The Nanny)

1. ross/rachel (friends)
2. castle/beckett (castle)
3. lucas/peyton (one tree hill)
4. meredith/derek (grey's anatomy)
5. barney/robin (himym)
6. neal/sara (white collar)
7. snow/charming (ouat)
8. robin/regina (ouat)
9. steve/miranda (satc)
10. monica/chandler (friends)
11. carrie/aidan (satc)
12. tyler/caroline (tvd)
13. alex/izzie (grey's anatomy)
14. will/emma (glee)
15. finn/rachel (glee)
16. callie/arizona (grey's anatomy)
17. puck/quinn (glee)
18. ryan/marissa (the oc)
19. hanna/caleb (pll)
20. graham/emma (ouat)
21. damon/elena (tvd)
22. owen/cristina (grey's anatomy)
23. spencer/toby (pll)
24. marshall/lily (himym)
25. nathan/haley (one tree hill)

1. Angel/Cordelia (Angel)
2. Bass/Rachel (Revolution)
3. Jack/Kate (Lost)
4. Ichabod/Abbie (Sleepy Hollow)
5. Shane/Lori (The Walking Dead)
6. Ted/Robin (HIMYM)
7. Alicia/Will (The Good Wife)
8. Holder/Linden (The Killing(
9. Hank/Marie (Breaking Bad)
10. Barney/Robin (HIMYM)
11. Cary/Robin (The Good Wife)
12. Frank/Jenny (Sleepy Hollow)
13. Booth/Bones (Bones)
14. Jin/Sun (Lost)
15. Rick/Andrea (The Walking Dead)
16. Daryl/Beth (The Walking Dead)
17. Connor/Charlie (Revolution)
18. Dean/Bela (Supernatural)
19. Damon/Katherine (The Vampire Diaries)
20. Emma/Graham (Once Upon a Time)
21. House/Cuddy (House MD)
22. Xander/Willow (Btvs)
23. Charlie/Claire (Lost)
24. Daniel/Charlotte (Lost)
25. Will/Beverly (Hannibal)

1. lucas&peyton (one tree hill)
2. freddie&effy (skins)
3. hook&emma (once upon a time)
4. sawyer&juliet (lost)
5. jackson&april (grey's anatomy)
6. logan&veronica (veronica mars)
7. jonny&jac (holby city)
8. barney&robin (how i met your mother)
9. jim&pam (the office)
10. dean&bela (supernatural)
11. tyler&caroline (the vampire diaries)
12. klaus&caroline (the vampire diaries)
13. oliver&felicity (arrow)
14. oliver&laurel (arrow)
15. nathan&haley (one tree hill)
16. jeff&annie (community)
17. alo&mini (skins)
18. jake&cassie (the secret circle)
19. brennan&kate (neighbours)
20. jack&kate (lost)
21. derek&meredith (grey's anatomy)
22. mark&addison (grey's anatomy)
23. mark&lexie (grey's anatomy)
24. neal&sara (white collar)
25. fitz&simmons (agents of shield)

1. Arthur & Guinevere (Merlin)
2. Mary & Bash (Reign)
3. Damon & Elena (The Vampire Diaries)
4. Mary & Matthew (Downton Abbey)
5. Scott & Stiles (Teen Wolf)
6. Freddie & Effy (Skins UK)
7. Brooke & Lucas (One Tree Hill)
8. Richard & Kahlan (Legend of the Seeker)
9. Sookie & Eric (True Blood)
10. Robin & Marian (Robin Hood BBC)
11. Abbie & Ichabod (Sleepy Hollow)
12. Greer & Leith (Reign)
13. Liam & Naomi (90210)
14. Sansa & Margaery (Game of Thrones)
15. Aurora & Mulan (Once Upon a Time)
16. Clarke & Bellamy (The 100)
17. Rory & Jess (Gilmore Girls)
18. Max & Liz (Roswell)
19. Emma & Thayer (The Lying Game)
20. Jeremy & Bonnie (The Vampire Diaries)
21. Daenerys & Jon (Game of Thrones)
22. Merlin & Morgana (Merlin)
23. Naomi & Emily (Skins UK)
24. Peter & Darcy (Degrassi)
25. Will & Djaq (Robin Hood BBC)

This will have to be canon and non-canon as I don't have many favorite canon couples.

1. Stiles/Derek - Teen Wolf
2. Spencer/Toby - Pretty little liars
3. Chandler/Monica - Friends
4. Jess/Nick - New Girl
5. Hanna/Caleb - Pretty little liars
6. Stefan/Elena - The Vampire Diaries
7. Scott/Allison - Teen Wolf
8. Pheobe/Mike - Friends
9. Caroline/Tyler - The Vampire Diaries
10. Marshall/Lily - How I met your Mother
11. Daenerys/Drogo - Game of thrones
12. Theo/Liam - Teen Wolf
13. Lucas/Peyton - One Tree Hill
14. Emily/Alison - Pretty little liars
15. Summer/Seth - The OC
16. Serena/Dan - Gossip Girl
17. Bonnie/Jeremy - The Vampire Diaries
18. Brooke/Lucas - One Tree Hill
19. Veronica/Logan - Veronica Mars
20. Kurt/Puck - Glee
21. Hyde/Jackie - That 70's Show
22. Ted/Tracey - How I met your Mother
23. Donna/Eric - That 70's Show
24. Rachel/Finn - Glee
25. DJ/Steve - Full House