Where is this Sam picture from? (Episode)

It's from second season, episode 20. What is and what should never be. Sam talks to Dean on phone and thinks he's drunk and at the end of this convertastion he smiles :)

this pic below is from the same scene :)

220 - what is and what should never be
the episode where the djinn puts dean under his "spell" it is from the scene where dean calls sam, but he doesn't realize what has happened yet.

not sure but i think its the one where dean is captured by the ggin and i cant think of the name