A list of the main and secondary villains of Batman's live-action films. The villains from Batman V Superman: Dawn Of Justice aren't listed, since that film's villains are Superman villains.
Batman: The Movie (1966)
Main antagonists: Penguin, Catwoman, Riddler, and Joker (Although if any of them is the main antagonist, it'd be Penguin, due to him being the leader.)
Batman (1989)
Main antagonist: Joker
Batman Returns (1992)
Main antagonists: Penguin, Catwoman, and Max Shreck
Batman Forever (1995)
Main antagonists: Two-Face and Riddler
Batman and Robin (1997)
Main antagonists: Mr. Freeze and Poison Ivy
Secondary antagonists: Bane and Dr. Woodrue
Batman Begins (2005)
Main antagonist: Ra's al Ghul
Secondary antagonists: Scarecrow and Carmine Falcone
The Dark Knight (2008)
Main antagonist: Joker
Secondary antagonists: Two-Face, the mob
The Dark Knight Rises (2012)
Main antagonists: Bane and Talia al Ghul
Cameo antagonist: Scarecrow
Secondary antagonists: Mr. Daggett, Catwoman (Catwoman robs Bruce in one scene, but she's more of an anti-hero in this film than a villain)
Cameo antagonists: Ra's al Ghul, Scarecrow
Batman: The Movie (1966)
Main antagonists: Penguin, Catwoman, Riddler, and Joker (Although if any of them is the main antagonist, it'd be Penguin, due to him being the leader.)
Batman (1989)
Main antagonist: Joker
Batman Returns (1992)
Main antagonists: Penguin, Catwoman, and Max Shreck
Batman Forever (1995)
Main antagonists: Two-Face and Riddler
Batman and Robin (1997)
Main antagonists: Mr. Freeze and Poison Ivy
Secondary antagonists: Bane and Dr. Woodrue
Batman Begins (2005)
Main antagonist: Ra's al Ghul
Secondary antagonists: Scarecrow and Carmine Falcone
The Dark Knight (2008)
Main antagonist: Joker
Secondary antagonists: Two-Face, the mob
The Dark Knight Rises (2012)
Main antagonists: Bane and Talia al Ghul
Cameo antagonist: Scarecrow
Secondary antagonists: Mr. Daggett, Catwoman (Catwoman robs Bruce in one scene, but she's more of an anti-hero in this film than a villain)
Cameo antagonists: Ra's al Ghul, Scarecrow