Ouma Shu from Guilty Crown
I don't have a picture of him being serious but
After one of his friends died which I think was Hare he became ruthless to everyone but for the sole reason of trying to make sure everyone survive
After temporarily becoming the Supreme King in season 3 of Yugioh Gx . Jaden in season 4 has lost the carefree personality he had before the incident and became a much more serious person . This is due to the fact that as the Supreme King Jaden hurt some of his closest friend and killed a lot of people .